Synthesis and complexation of heptafluoroisopropyldiphenylphosphine.
نویسندگان
چکیده
We report a one-step synthesis of the phosphine, PPh(2)(i)C(3)F(7) from commercially available precursors. The stereoelectronic properties of the phosphine were probed by coordination to transition metals. Mo(CO)(5)PPh(2)(i)C(3)F(7) was synthesised and the synthesis and structure of trans-PtCl(2)(PPh(2)(i)C(3)F(7))(2) are described. PPh(2)(i)C(3)F(7) was found to be a bulky electron-withdrawing ligand.
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 5 شماره
صفحات -
تاریخ انتشار 2010